Cerium Element Facts / Chemistry


TEM image of a cerium oxide nanorod formed in an ice channel.

TEM image of a cerium oxide nanorod formed in an ice channel. Image Ref.(6)

58
Ce
140.1

Data Zone

Classification: Cerium is a lanthanide and rare earth metal
Color: gray
Atomic weight: 140.12
State: solid
Melting point: 798 oC, 1071 K
Boiling point: 3443 oC, 3716 K
Electrons: 58
Protons: 58
Neutrons in most abundant isotope: 82
Electron shells: 2,8,18,20,8,2
Electron configuration: [Xe] 4f2 6s2
Density @ 20oC: 6.78 g/cm3
Show more, including: Heats, Energies, Oxidation, Reactions, Compounds, Radii, Conductivities
Atomic volume: 20.67 cm3/mol
Structure: fcc: face-centered cubic
Hardness: 2.5 mohs
Specific heat capacity 0.19 J g-1 K-1
Heat of fusion 5.460 kJ mol-1
Heat of atomization 419 kJ mol-1
Heat of vaporization 313.8 kJ mol-1
1st ionization energy 534.4 kJ mol-1
2nd ionization energy 1050 kJ mol-1
3rd ionization energy 1949 kJ mol-1
Electron affinity 50 kJ mol-1
Minimum oxidation number 0
Min. common oxidation no. 0
Maximum oxidation number 4
Max. common oxidation no. 4
Electronegativity (Pauling Scale) 1.12
Polarizability volume 29.6 Å3
Reaction with air vigorous, w/ht ⇒ CeO2
Reaction with 15 M HNO3 mild, ⇒ Ce(NO3)3
Reaction with 6 M HCl vigorous, ⇒ H2, CeCl3
Reaction with 6 M NaOH
Oxide(s) Ce2O3, CeO2 (ceria)
Hydride(s) CeH2, CeH3
Chloride(s) CeCl3
Atomic radius 185 pm
Ionic radius (1+ ion)
Ionic radius (2+ ion)
Ionic radius (3+ ion) 115 pm
Ionic radius (1- ion)
Ionic radius (2- ion)
Ionic radius (3- ion)
Thermal conductivity 11.3 W m-1 K-1
Electrical conductivity 1.4 x 106 S m-1
Freezing/Melting point: 798 oC, 1071 K



Jöns Jacob Berzelius

Jöns Jacob Berzelius. Berzelius portrait from Royal Swedish Academy of Sciences

Discovery of Cerium

Dr. Doug Stewart

Cerium was discovered in 1803 by Jöns J. Berzelius and Wilhelm von Hisinger in Sweden, and independently in the same year by Martin Klaproth in Germany.

Berzelius and Hisinger discovered the new element in a rare reddish-brown mineral now known as cerite, a cerium-lanthanide silicate. (1), (2)

Berzelius and Hisinger prepared cerium salts from cerite and investigated their chemical reactions. Although they could not isolate the pure metal, they found that cerium had two oxidation states: one yielding colorless salts, the other yellow-red ones. (1), (3)

They named the new element cerium after the asteroid Ceres, which had been discovered just two years earlier by Giuseppe Piazzi. They called cerium oxide ‘ceria.’

Klaproth’s analysis of the mineral also indicated that it contained the oxide of a new element. He named the oxide ockroite after its yellowish red color. (1), (3)

Berzelius and Hisinger published their results before Klaproth and the name cerium was accepted for the new metal.

Berzelius and Klaproth are major figures in the history of chemistry. In addition to their other achievements Berzelius discovered selenium in 1817 and thorium in 1828 while in 1789 Klaproth discovered both uranium and zirconium.

Carl G. Mosander, who worked closely with Berzelius, prepared metallic cerium in 1825. First he reacted cerium sulfide with chlorine, yielding anhydrous cerium chloride. He reduced the chloride with potassium, forming potassium chloride and metallic cerium. He burnished the resulting brown powder to obtain a gray material with a dull metallic luster – cerium, although rather impure. (3a), (4)

Mosander’s isolation of cerium from its chloride using potassium was similar to the approach used by Ørsted to isolate aluminum in 1825. Subsequently Wöhler and Bussy used this method to isolate beryllium in 1828 and in the same year Berzelius used it to isolate thorium.

Mosander continued to investigate cerite chemistry and in 1839 he discovered the new element lanthanum, which is also present in cerite.

Mischmetal

Mischmetal is an alloy of cerium and lanthanum, with small amounts of neodymium and praseodymium. photo:Spypredator

cerium-oxide-catalyst

Researchers in Argonne’s Chemical Engineering Division have developed a catalyst that could help diesel truck manufacturers eliminate harmful nitrogen-oxide (NOx) emissions from diesel exhausts. The beaker of blue catalyst material is ‘Cu-ZSM-5′, a zeolite with copper ions attached within its micropore structure and an external coating of cerium oxide. photo: Argonne National Lab


Appearance and Characteristics

Harmful effects:

Cerium is considered to be moderately toxic.

Characteristics:

Cerium is a reactive, soft, gray, lustrous metal that is malleable and ductile.

When present in compounds, cerium exists in both the trivalent state (Ce3+, cerous, usually orange-red) and the tetravalent state (Ce4+, ceric , usually colorless).

The metal tarnishes in moist air and reacts with water to form cerium hydroxide plus hydrogen gas.

Small particles of the metal may ignite if a knife scratches the pure metal surface.

It is attacked by alkali solutions and all acids.

Cerium has a variable electronic structure: the energy of the inner 4f level is nearly the same as that of the 6s level, allowing variable occupancy of these two levels.

Uses of Cerium

An alloy of cerium and lanthanum, with small amounts of neodymium and praseodymium (misch metal) combined with iron oxide and magnesium oxide is used as the flint in cigarette and gas lighters.

Cerium is used in carbon-arc lighting, especially in the motion picture industry. It is also used in phosphors for color television screens and fluorescent lighting.

Cerium oxide is used as a catalytic converter to reduce carbon monoxide emissions in the exhaust fumes from automobiles. Cerium oxide, as a nanopowder, is added to diesel fuel to reduce sooty fumes and improve engine performance. It is used in the walls of self-cleaning ovens and is also used to polish glass surfaces.

Flammacerium (cerium nitrate-silver sulphadiazine) is a cream to treat and prevent infections in extensive burn wounds. The cerium nitrate component reduces the occurrence of immunosuppression. (5)

Abundance and Isotopes

Abundance earth’s crust: 60 parts per million by weight, 8.9 parts per million by moles

Abundance solar system: 4 parts per billion by weight, 30 parts per trillion by moles

Cost, pure: $380 per 100g

Cost, bulk: $1.20 per 100g

Source: Cerium is the most abundant of the lanthanides. It is not found free in nature but is found in a number of minerals, mainly allanite, bastnasite and monazite. Commercially, cerium is prepared by electrolysis of the chloride or by reduction of the fused fluoride with calcium.

Isotopes: Cerium has 30 isotopes whose half-lives are known, with mass numbers 123 to 152. Naturally occurring cerium is a mixture of four isotopes and they are found in the percentages shown: 136Ce (0.2%), 138Ce (0.3%), 140Ce (88%) and 142Ce (11%).

References

1. Johan Erik Jorpes, Jac. Berzelius: his life and work., 1970 p26-27, University of California Press.
2. Paul Caro, Rare earths., Editorial Complutense, 1998 p30-31.
3. Per Enghag, Encyclopedia of the elements: technical data, history, processing, applications., 2004, p438, John Wiley and Sons.
3a. Per Enghag, Encyclopedia of the elements: technical data, history, processing, applications., 2004, p444, John Wiley and Sons.
4. Leopold Gmelin, Hand-book of chemistry, Volume 3, Metals, 1849, p257, Harrison and Son.
5. Sinclair Pharma plc pdf
6. Image Ref. EMSL

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