Iridium Element Facts


Iridium rich layer (K-T boundary) which marks the demise of the dinosaurs.

Iridium rich layer (K-T boundary) which marks the demise of the dinosaurs. Image Ref. (1)

77
Ir
192.2

Data Zone

Classification: Iridium is a transition metal
Color: silvery-white
Atomic weight: 192.22
State: solid
Melting point: 2447 oC, 2720 K
Boiling point: 4430 oC, 4703 K
Electrons: 77
Protons: 77
Neutrons in most abundant isotope: 116
Electron shells: 2,8,18,32,15,2
Electron configuration: [Xe] 4f14 5d7 6s2
Density @ 20oC: 22.56 g/cm3
Show more, including: Heats, Energies, Oxidation, Reactions, Compounds, Radii, Conductivities
Atomic volume: 8.54 cm3/mol
Structure: fcc: face-centered cubic
Hardness: 6.5 mohs
Specific heat capacity 0.13 J g-1 K-1
Heat of fusion 26.10 kJ mol-1
Heat of atomization 671 kJ mol-1
Heat of vaporization 563 kJ mol-1
1st ionization energy 880 kJ mol-1
2nd ionization energy 1600 kJ mol-1
3rd ionization energy
Electron affinity 151 kJ mol-1
Minimum oxidation number -1
Min. common oxidation no. -1
Maximum oxidation number 6
Max. common oxidation no. 4
Electronegativity (Pauling Scale) 2.2
Polarizability volume 7.6 Å3
Reaction with air none
Reaction with 15 M HNO3 none
Reaction with 6 M HCl none
Reaction with 6 M NaOH none
Oxide(s) IrO2, Ir2O3
Hydride(s)
Chloride(s) IrCl2, IrCl3, IrCl4
Atomic radius 136 pm
Ionic radius (1+ ion)
Ionic radius (2+ ion)
Ionic radius (3+ ion) 82 pm
Ionic radius (1- ion)
Ionic radius (2- ion)
Ionic radius (3- ion)
Thermal conductivity 147 W m-1 K-1
Electrical conductivity 21.3 x 106 S m-1
Freezing/Melting point: 2447 oC, 2720 K



Discovery of Iridium

Iridium was discovered in 1803, by English chemist Smithson Tennant in London.

He found it in the residue left when crude platinum had been dissolved in aqua regia (a mixture of hydrochloric acid and nitric acid).

Smithson Tennant also discovered osmium at the same time.

Iridium’s name comes from the Latin word ‘iris’, meaning rainbow, because many of its salts are highly colored.

Abnormally high amounts of iridium have been found in rocks dating to the K-T boundary between the Cretaceous and Tertiary periods (65 million years ago).

This has led to a widely held view that an iridium-containing comet struck the Earth at that time, which led to the extinction of the dinosaurs and many other forms of life.

Iridium

Iridium metal. Photo by Dschwen.

Appearance and Characteristics

Harmful effects:

Iridium is considered to be of low toxicity.

Iridium in powder form is a known irritant and is a fire hazard.

Characteristics:

Iridium is a rare, hard, lustrous, brittle, very dense platinum-like metal.

Chemically it is very unreactive.

It is the most corrosion-resistant metal known and it resists attack by any acid.

Iridium is attacked by molten salts such as sodium chloride (NaCl) and sodium cyanide (NaCN).

Iridium is generally credited with being the second densest element (after osmium) based on measured density, although calculations involving the space lattices of the elements show that iridium is denser.

Uses of Iridium

The main use of iridium is as a hardening agent for platinum alloys.

With osmium, it forms an alloy that is used for tipping pens, and compass bearings.

Iridium is used in making crucibles and other equipment that is used at high temperatures.

It is also used to make heavy-duty electrical contacts.

Iridium was used in making the international standard kilogram, which is an alloy of 90% platinum and 10% iridium.

Radioactive isotopes of iridium are used in radiation therapy for the treatment of cancer.

Abundance and Isotopes

Abundance earth’s crust: 0.4 parts per billion by weight, 0.05 parts per billion by moles

Abundance solar system: 2 parts per billion by weight, 0.01 parts per billion by moles

Cost, pure: $4200 per 100g

Cost, bulk: $2300 per 100g

Source: Iridium is found in natural alloys with platinum and osmium in alluvial deposits. Commercially, iridium is recovered as a by-product from the nickel mining industry.

Isotopes: Iridium has 34 isotopes whose half-lives are known, with mass numbers from 165 to 198. Naturally occurring iridium is a mixture of two isotopes: 191Ir and 193Ir with natural abundances of 37.3% and 62.7% respectively.

References

1. U.S. Geological Survey

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Comments

  1. theskyserpent says:

    most corrrosion-resistance metal? cool!

  2. jaden moore says:

    where can i find iridium

  3. I think iridum is in most all LCD screens. And by collecting these screens, if you get enough you can make yourself a few extra dollars. Would I be correct in my thinking?

  4. Yes but very little. So you wouldnt make a good profit from it.

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