Neodymium Element Facts / Chemistry


Martian Meteorite, whose age is revealed by the amount of neodymium and tungsten isotopes it contains.

Meteorite ALH84001. This meteorite, found in Antarctica, may contain fossils of primitive Martian life from over 3.6 billion years ago. The ages and timelines of Martian rock formation can be calculated from the amount of neodymium and tungsten isotopes present. Photo: Nasa

60
Nd
144.2

Data Zone

Classification: Neodymium is a lanthanide and rare earth metal
Color: silvery-white
Atomic weight: 144.24
State: solid
Melting point: 1016 oC, 1289 K
Boiling point: 3070 oC, 3343 K
Electrons: 60
Protons: 60
Neutrons in most abundant isotope: 82
Electron shells: 2,8,18,22,8,2
Electron configuration: [Xe] 4f4 6s2
Density @ 20oC: 7.0 g/cm3
Show more, including: Heats, Energies, Oxidation, Reactions, Compounds, Radii, Conductivities
Atomic volume: 20.6 cm3/mol
Structure: close packed (ABCB)
Hardness:
Specific heat capacity 0.19 J g-1 K-1
Heat of fusion 7.140 kJ mol-1
Heat of atomization 328 kJ mol-1
Heat of vaporization 283.68 kJ mol-1
1st ionization energy 529.6 kJ mol-1
2nd ionization energy 1035 kJ mol-1
3rd ionization energy 2130 kJ mol-1
Electron affinity 50 kJ mol-1
Minimum oxidation number 0
Min. common oxidation no. 0
Maximum oxidation number 3
Max. common oxidation no. 3
Electronegativity (Pauling Scale) 1.14
Polarizability volume 31.4 Å3
Reaction with air mild, ⇒ Nd2O3
Reaction with 15 M HNO3 mild, ⇒ Nd(NO3)3
Reaction with 6 M HCl mild, ⇒ H2, NdCl3
Reaction with 6 M NaOH
Oxide(s) Nd2O3
Hydride(s) NdH2, NdH3
Chloride(s) NdCl2, NdCl3
Atomic radius 185 pm
Ionic radius (1+ ion)
Ionic radius (2+ ion) 143 pm
Ionic radius (3+ ion) 112.3 pm
Ionic radius (1- ion)
Ionic radius (2- ion)
Ionic radius (3- ion)
Thermal conductivity 16.5 W m-1 K-1
Electrical conductivity 1.6 x 106 S m-1
Freezing/Melting point: 1016 oC, 1289 K



Neodymium uses

Neodymium is used in hybrid car electric motors and generators, cell phones, iPods and wind turbines.

Discovery of Neodymium

Dr. Doug Stewart

Neodymium was first identified in 1885, in Vienna, by Austrian scientist Carl Auer von Welsbach. It was discovered in ‘didymium,’ a substance incorrectly identified by Swedish chemist Carl Mosander as a new element in 1841. (1)

The nonexistent ‘didymium’ was even given the symbol Di in Mendeleev’s first edition of the periodic table in 1869.

In 1879 French chemist Lecoq de Boisbaudran detected and separated samarium from ‘didymium’ in Paris. (1a)

After samarium had been discovered, it was noted that ‘didymium’s’ absorption spectrum gave different results depending on which mineral it had been sourced from. (2)

Bohuslav Brauner working in Prague, published a paper on atomic weight determinations in 1882 for rare earth elements and his data for ‘didymium’ were variable.

Brauner became convinced that ‘didymium’ was a mixture of elements; he attempted to separate them, but he was not successful. (2)

In 1885 Carl Welsbach, who had discovered ‘didymium’ 14 years earlier, realized it was actually a mixture of two entirely new elements.

He named these neodymium and praseodymium. Welsbach reacted ‘didymium’ to form nitrate salts, which he then fractionally crystallized from nitric acid to yield pink neodymium and greenish-brown praseodymium salts.

The fractional crystallization experiments were very time consuming, involving more than one hundred crystallization operations, each lasting up to 48 hours.

Neodymium was named with ‘neos didymos’ – Greek for ‘new twin,’ reflecting neodymium’s close association with praseodymium.

Pure neodymium metal was isolated in 1925 by H. Kremers.

A neodymium magnet acts as a weight lifter.

Neodymium YAG laser

A “neodymium-YAG” (Nd:YAG) laser can be used for decontamination after detonation of a chemical weapon. For example, it can decompose a nerve agent, shown on tile on the right. The laser emits UV light which breaks the molecular bonds, decomposing the nerve agent until it is a harmless brown stain. Photo: Homeland Security


Appearance and Characteristics

Harmful effects:

Neodymium is considered to be moderately toxic.

Characteristics:

Neodymium is a soft, bright, silvery white metal. It is one of the lanthanide rare earth metals. It forms a flaky oxide coating in air. Unlike many metal oxide layers, this one does not protect the metal from further oxidation.

Neodymium has two allotropic forms, transforming from hexagonal to body-centered cubic above 800K (527 oC).

Neodymium usually exists as a trivalent ion, Nd3+, in its compounds. Most of its salts are pale purple in color.

Uses of Neodymium

Neodymium is used with iron and boron to create powerful permanent magnets, also called NIB magnets. NIB magnets are used in computers, cell phones, medical equipment, toys, motors, wind turbines and audio systems. (3)

Neodymium is used as a crystal (neodymium-doped yttrium aluminum garnet) in lasers. These ND:YAG lasers have numerous applications. For example, they are used in medicine to treat skin cancers and for laser hair removal; and in industry they are used to cut and weld steel.

Neodymium is used to make specialized goggles for glass blowers.

The metal is also used in a spark producing alloy (misch metal) for cigarette lighter flints.

Neodymium salts are used to color glasses and enamels.

Abundance and Isotopes

Abundance earth’s crust: 33 parts per million by weight, 4.8 parts per million by moles

Abundance solar system: 3 parts per billion by weight, 20 parts per trillion by moles

Cost, pure: $420 per 100g

Cost, bulk: $ per 100g

Source: Neodymium is not found free in nature but is found in a number of minerals – mainly monazite and bastnaesite. Commercially it is extracted from monazite and bastnaesite by ion exchange and solvent extraction processes. Neodymium metal can be made by the reduction of anhydrous halides with calcium metal.

Isotopes: Neodymium has 30 isotopes whose half-lives are known, with mass numbers 127 to 156. Naturally occurring neodymium is a mixture of seven isotopes and they are found in the percentages shown: 142Nd (27.2%), 143Nd (12.2%), 144Nd (23.8%), 145Nd (8.3%), 146Nd (17.2%), 148Nd (5.7%) and 150Nd (5.6%). The most abundant isotope is 142Nd at 27.2%.

References

1. David R. Lide, CRC Handbook of the Chemistry and Physics 86th Edition., Taylor and Francis., 2005, 4-23.
1a. David R. Lide, CRC Handbook of the Chemistry and Physics 86th Edition., Taylor and Francis., 2005, 4-32.
2. Ferenc Szabadváry, Handbook of the Chemistry and Physics of the Rare Earths Vol. 11., Elsevier Science Publishers., 1998, p61.
3. Ningbo Bei Ke Strong Magnetic Material Co., Ltd., Neo magnets.

Cite this Page

For online linking, please copy and paste one of the following:

<a href="http://www.chemicool.com/elements/neodymium.html">Neodymium</a>

or

<a href="http://www.chemicool.com/elements/neodymium.html">Neodymium Element Facts</a>

To cite this page in an academic document, please use the following MLA compliant citation:

"Neodymium." Chemicool Periodic Table. Chemicool.com. 17 Oct. 2012. Web.  
<http://www.chemicool.com/elements/neodymium.html>.