89
Ac
227
Actinium
General | States | Energies
Oxidation & Electrons | Appearance & Characteristics
Reactions | Compounds | Radius | Conductivity
Abundance & Isotopes

Actinium Radioactive




General:

Name: Actinium Symbol: Ac
Type: Transition Metal / Actinoid (Actinide) Atomic weight: 227.0278
Density @ 293 K: 10.07 g/cm3 Atomic volume: 22.54 cm3/mol
Discovered: by Andre Debierne in 1899. Debierne worked with Marie Curie and discovered actinium in pitchblende (uranium ore) from which radium and polonium had already been extracted. He was able to identify the presence of a new element because the radioactive emissions profile of his sample could not be explained by the presence of any known element. Debierne was unable to isolate pure actinium from the thorium also present in pitchblende.

States

State (s, l, g): solid
Melting point: 1323.2 K   (1050 oC) Boiling point: 3471 K   (3199 oC)

Energies

Specific heat capacity: 27.2 J mol-1 K-1 Heat of atomization: 406 kJ mol-1 ?
Heat of fusion: 14.2 kJ mol-1 Heat of vaporization: 400 kJ mol-1
1st ionization energy: 499 kJ mol-1 2nd ionization energy: 1170 kJ mol-1
3rd ionization energy: kJ mol-1 Electron affinity: kJ mol-1

Oxidation & Electrons

Shells: 2,8,18,32,18,9,2 Electron configuration: [Rn] 6d1 7s2
Minimum oxidation number: 0 Maximum oxidation number: 3
Min. common oxidation no.: 0 Max. common oxidation no.: 3
Electronegativity (Pauling Scale): 1.1 Polarizability volume: 32.1 Å3

Appearance & Characteristics

Structure: fcc: face-centered cubic Color: silvery-white
Uses: neutron production Hardness: mohs
Harmful effects: highly radioactive
Characteristics: radioactive, glows in the dark

Reactions

Reaction with air: mild, w/ht, ⇒ Ac2O3 Reaction with 6 M HCl: mild, ⇒ H2, AcCl3
Reaction with 15 M HNO3: mild, ⇒ Ac(NO3)3 Reaction with 6 M NaOH:

Compounds

Oxide(s): Ac2O3 Chloride(s): AcCl3
Hydride(s): AcH2

Radius

Atomic radius: 195 pm Ionic radius (1+ ion): pm
Ionic radius (2+ ion): pm Ionic radius (3+ ion): 112 pm
Ionic radius (2- ion): pm Ionic radius (1- ion): pm

Conductivity

Thermal conductivity: W m-1 K-1 Electrical conductivity: S m-1

Abundance & Isotopes

Abundance earth's crust: 0.0005 parts per trillion by weight
Abundance solar system: negligible
Cost, pure: $ per 100g
Cost, bulk: $ per 100g
Source: Natural U-235 radioactive decay. A ton of pitcheblende contains about 0.15 milligrams of actinium. Nowadays, actinium is generally produced by the neutron irradiation of 226Ra.
Isotopes: Actinium has 29 isotopes. All are radioactive. 227Ac occurs naturally in uranium ore and, at 21.773 years, has the longest Ac half-life.