General
States
Energies
Oxidation & Electrons
Appearance & Characteristics
Reactions & Compounds
Radius
Conductivity
Abundance & Isotopes
States
Energies
Oxidation & Electrons
Appearance & Characteristics
Reactions & Compounds
Radius
Conductivity
Abundance & Isotopes
|
96
Cm
247
Curium |
Curium is Radioactive.
General:
Name: Curium
Type: Actinide
Density @ 293 K: 13.5 g/cm3
Discovery of Curium
Curium was the third synthetic transuranium element of the actinide series to be discovered.
It was discovered by Glenn T. Seaborg, Ralph A.James, and Albert Ghiorso in 1944. Curium-242 (half-life 162.8 days) was produced by bombarding plutonium-239 with alpha particles in the Berkeley, California, 60-inch cyclotron. Each nuclear reaction produced a neutron in addition to an atom of curium-242. (1)
The element was chemically identified at the metallurgical laboratory at the University of Chicago.
The researchers at first referred to curium as "delirium" owing to the difficulties they encountered trying to isolate it from another new element with which it was very closely associated, americium - or "pandemonium" as it was first called.
Type: Actinide
Density @ 293 K: 13.5 g/cm3
Discovery of Curium
Curium was the third synthetic transuranium element of the actinide series to be discovered.
It was discovered by Glenn T. Seaborg, Ralph A.James, and Albert Ghiorso in 1944. Curium-242 (half-life 162.8 days) was produced by bombarding plutonium-239 with alpha particles in the Berkeley, California, 60-inch cyclotron. Each nuclear reaction produced a neutron in addition to an atom of curium-242. (1)
The element was chemically identified at the metallurgical laboratory at the University of Chicago.
The researchers at first referred to curium as "delirium" owing to the difficulties they encountered trying to isolate it from another new element with which it was very closely associated, americium - or "pandemonium" as it was first called.
Symbol: Cm
Atomic weight: 247
Atomic volume: 18.28 cm3/mol
Atomic weight: 247
Atomic volume: 18.28 cm3/mol
Visible amounts of curium-242, in the form of curium hydroxide, were first isolated by Louis Werner and Isadore Perlman of the University of California in 1947. Curium-242 was produced by bombarding americium-241 with slow moving neutrons for a year. (2)
In 1952, W. W. Crane, J. C. Wallmann, and Burris B.Cunningham prepared metallic curium for the first time. (3)
The element is named after Marie Curie and her husband Pierre, who pioneered work on radioactivity and discovered radium and polonium.
States
State (s, l, g): solid
Melting point: 1613 K (1340 oC)
Melting point: 1613 K (1340 oC)
Boiling point: 3373 K (3100 oC)
Energies
Specific heat capacity: J g-1 K-1
Heat of fusion: kJ mol-1
1st ionization energy: 581 kJ mol-1
3rd ionization energy: kJ mol-1
Heat of fusion: kJ mol-1
1st ionization energy: 581 kJ mol-1
3rd ionization energy: kJ mol-1
Heat of atomization: kJ mol-1
Heat of vaporization: kJ mol-1
2nd ionization energy: kJ mol-1
Electron affinity: kJ mol-1
Heat of vaporization: kJ mol-1
2nd ionization energy: kJ mol-1
Electron affinity: kJ mol-1
Oxidation & Electrons
Shells: 2,8,18,32,25,9,2
Minimum oxidation number: 0
Min. common oxidation no.: 0
Electronegativity (Pauling Scale): 1.3
Minimum oxidation number: 0
Min. common oxidation no.: 0
Electronegativity (Pauling Scale): 1.3
Electron configuration: [Rn] 5f7 6d1 7s2
Maximum oxidation number: 4
Max. common oxidation no.: 3
Polarizability volume: 23 Å3
Maximum oxidation number: 4
Max. common oxidation no.: 3
Polarizability volume: 23 Å3
Appearance & Characteristics
Structure: fcc: face-centered cubic
Hardness: mohs
Hardness: mohs
The Alpha Particle X-Ray Spectrometer (APXS) used on the Mars Exploration Rovers.
It uses small amounts of curium-244 to determine the concentrations of most major elements in rocks and soil.
(Photo credit: NASA)
Color: silvery-white
Harmful effects:
Curium is harmful due to its radioactivity. It accumulates in bones and destroys the marrow, stopping the formation of red blood cells.
Characteristics:
Curium is a hard, dense radioactive silvery-white metal. It tarnishes slowly in dry air at room temperature. Most compounds of trivalent curium are slightly yellow in color.
Curium is highly radioactive and it glows red in the dark. (4)
Uses:
Curium is mainly used for scientific research purposes. Curium-244 was used in the Alpha Proton X-ray Spectrometer (APXS) which measured the abundance of chemical elements in rocks and soils on Mars. Curium-244 is a strong alpha emitter and is being studied as a potential power source in radioisotope thermoelectric generators (RTGs) for use in spacecraft and other remote applications.
Harmful effects:
Curium is harmful due to its radioactivity. It accumulates in bones and destroys the marrow, stopping the formation of red blood cells.
Characteristics:
Curium is a hard, dense radioactive silvery-white metal. It tarnishes slowly in dry air at room temperature. Most compounds of trivalent curium are slightly yellow in color.
Curium is highly radioactive and it glows red in the dark. (4)
Uses:
Curium is mainly used for scientific research purposes. Curium-244 was used in the Alpha Proton X-ray Spectrometer (APXS) which measured the abundance of chemical elements in rocks and soils on Mars. Curium-244 is a strong alpha emitter and is being studied as a potential power source in radioisotope thermoelectric generators (RTGs) for use in spacecraft and other remote applications.
Reactions & Compounds
Reaction with air:
Reaction with 15 M HNO3:
Oxide(s): CmO, Cm2O3, CmO2
Hydride(s): CmH2
Reaction with 15 M HNO3:
Oxide(s): CmO, Cm2O3, CmO2
Hydride(s): CmH2
Reaction with 6 M HCl:
Reaction with 6 M NaOH:
Chloride(s): CmCl3
Reaction with 6 M NaOH:
Chloride(s): CmCl3
Radius
Atomic radius: 174 pm
Ionic radius (2+ ion): pm
Ionic radius (2- ion): pm
Ionic radius (2+ ion): pm
Ionic radius (2- ion): pm
Ionic radius (1+ ion): pm
Ionic radius (3+ ion): 111 pm
Ionic radius (1- ion): pm
Ionic radius (3+ ion): 111 pm
Ionic radius (1- ion): pm
Conductivity
Thermal conductivity: W m-1 K-1
Electrical conductivity: x 106 S cm-1
Abundance & Isotopes
Abundance earth's crust: nil
Abundance solar system: unkmown
Cost, pure: $ per g
Cost, bulk: per 100g
Source: Curium does not exist in nature. It is a synthetic element and it is produced in nuclear reactors by bombarding plutonium with neutrons.
Isotopes: Curium has 15 isotopes whose half-lives are known, with mass numbers 238 to 252. Curium has no naturally occuring isotopes. Its longest lived isotopes are 247Cm, with a half-life of 15.6 million years, 248Cm with a half-life of 340,000 years and 250Cm with a half-life of 9,000 years.
Abundance solar system: unkmown
Cost, pure: $ per g
Cost, bulk: per 100g
Source: Curium does not exist in nature. It is a synthetic element and it is produced in nuclear reactors by bombarding plutonium with neutrons.
Isotopes: Curium has 15 isotopes whose half-lives are known, with mass numbers 238 to 252. Curium has no naturally occuring isotopes. Its longest lived isotopes are 247Cm, with a half-life of 15.6 million years, 248Cm with a half-life of 340,000 years and 250Cm with a half-life of 9,000 years.
References
1. Thomas K. Keenan, Americium and Curium., Journal of Chemical Education 36.1 (1959) p27.
2. J. C. Wallmann, The First Isolations of the Transuranium Elements., Journal of Chemical Education 36.7 (1959) p343.
3. Glenn Theodore Seaborg, The transuranium elements ., Taylor & Francis, 1958., page 93
4. Open Learn Labspace
2. J. C. Wallmann, The First Isolations of the Transuranium Elements., Journal of Chemical Education 36.7 (1959) p343.
3. Glenn Theodore Seaborg, The transuranium elements ., Taylor & Francis, 1958., page 93
4. Open Learn Labspace
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