General
States
Energies
Oxidation & Electrons
Appearance & Characteristics
Reactions
Compounds
Radius
Conductivity
Abundance & Isotopes



73
Ta
180.947
Tantalum
Tantalum
High Purity Tantalum (Photo: Tomihahndorf)

General:

Name: Tantalum Symbol: Ta
Type: Transition Metal Atomic weight: 180.947
Density @ 293 K: 16.6 g/cm3 Atomic volume: 10.90 cm3/mol
Discovered: Tantalum was discovered by Anders G. Ekeberg in 1802 and was first isolated in 1820 by Jöns Berzelius. The element name comes from the Greek mythological character Tantalos, father of Niobe.

States

State (s, l, g): solid
Melting point: 3293 K   (3020 oC) Boiling point: 5833 K   (5560 oC)

Energies

Specific heat capacity: 0.14 J g-1 K-1 Heat of atomization: 782 kJ mol-1
Heat of fusion: 36.57 kJ mol-1 Heat of vaporization : 737 kJ mol-1
1st ionization energy: 761 kJ mol-1 2nd ionization energy: 1500 kJ mol-1
3rd ionization energy: kJ mol-1 Electron affinity: 31.1 kJ mol-1

Oxidation & Electrons

Shells: 2,8,18,32,11,2 Electron configuration: [Xe] 4f14 5d3 6s2
Minimum oxidation number: -1 Maximum oxidation number: 5
Min. common oxidation no.: 0 Max. common oxidation no.: 5
Electronegativity (Pauling Scale): 1.5 Polarizability volume: 13.1 Å3

Appearance & Characteristics

Structure: bcc: body-centered cubic Color: gray
Harmful effects: Tantalum is considered to be non-toxic. Hardness: 6.5 mohs
Characteristics: Tantalum is a rare, shiny, gray, dense metal. It is highly ductile and can be drawn into a thin wire. Its chemical properties are very similar to those of niobium. Tantalum is highly corrosion resistant due to the formation of an oxide film. It is an excellent conductor of heat and electricity. The metal has a melting point exceeded only by tungsten and rhenium. Tantalum is one of the five major refractory metals (metals with very high resistance to heat and wear). The other refactory metals are tungsten, molybdenum, rhenium and niobium.
Uses: Tantalum is used in the electronics industry for capacitors and high power resistors. It is also used to make alloys to increase strength, ductility and corrosion resistance. The metal is used in dental and surgical instruments and implants, as it causes no immune response.

Reactions

Reaction with air: none Reaction with 6 M HCl: none
Reaction with 15 M HNO3: none Reaction with 6 M NaOH: none

Compounds

Oxide(s): TaO2, Ta2O5 Chloride(s): TaCl3, TaCl4, TaCl5
Hydride(s): Ta2H

Radius

Atomic radius: 146 pm Ionic radius (1+ ion): pm
Ionic radius (2+ ion): pm Ionic radius (3+ ion): 86 pm
Ionic radius (2- ion): pm Ionic radius (1- ion): pm

Conductivity

Thermal conductivity: 57.5 W m-1 K-1 Electrical conductivity: 8.1 x 106 S m-1

Abundance & Isotopes

Abundance earth's crust: 1.7 parts per million by weight, 0.2 parts per million by moles
Abundance solar system: parts per billion by weight, parts per billion by moles
Cost, pure: $450 per 100g
Cost, bulk: $8.10 per 100g
Source: Tantalum is not found free in nature but in minerals such as columbite and tantalite. Minerals that contain tantalum often also contain niobium. Commercially, tantalum is extracted by first forming the oxide (Ta2O5). The oxide is then reduced using carbon or hydrogen.
Isotopes: Tantalum has 31 isotopes whose half-lives are known, with mass numbers from 156 to 186. Of these, one is stable, 181Ta.