113
Uut
286
Ununtrium
Ununpentium will decay into ununtrium by emission of an alpha particle. Image: LLNL
Classification:Ununtrium is an 'other metal' (presumed)
Atomic weight: 286 g/mol
Density @ 20 oC: g/cm3
Atomic volume: cm3/mol
Element 115 decay
Heavy elements 113 and 115 may have been made after combining calcium-48 and amercium-243. Image: LLNL.

Discovery of Ununtrium


Author: Dr. Doug Stewart

Research scientists at the Joint Institute for Nuclear Research in Dubna, Russia and the Lawrence Livermore National Laboratory (LLNL), California believed they had made element 113, ununtrium, in Dubna, Russia in 2003. The work was a collaboration between science teams led by Yuri Oganessian and Ken Moody.

The team gathered data indicating that element 113 had been made by alpha decay of element 115. Element 115 was synthesized by fusion of element 20 with element 95: calcium-48 with americium-243.

The experiment began on July 14, 2003, and ended on August 10, 2003. Calcium ions were formed into a beam in a cyclotron (a particle accelerator) and fired at a target layer of americium deposited on titanium foil. Four atoms of element 115 (ununpentium) may have been produced, which then decayed to element 113 (ununtrium). (1)

The researcher's data indicates one atom of ununtrium-283 and three atoms of ununtrium-284 were made. (2)

In 2011, The International Union of Pure and Applied Chemistry (IUPAC) reviewed the work done in Dubna and at the LLNL, and did not accept the discovery of ununtrium.

The report stated, "the results are encouraging but do not meet the criteria for discovery because of the paucity of events, the lack of connections to known nuclides, and the absence of cross-bombardments." (3)

As a result of its position in the periodic table, ununtrium would be expected to be classed as one of the "other metals" and to have similar properties to the metal thallium. Too little of the element has been synthesized for this to be confirmed.

The joint teams at JINR in Dubna and Lawrence Livermore in California have published evidence for the synthesis of elements 113, 114, 115, 116, 117 and 118.

IUPAC has accepted the discoveries of element 114 (ununquadium) and element 116 (ununhexium). It has not yet considered the evidence for the discovery of element 117 (ununseptium).

IUPAC requires stronger evidence before it will confirm the synthesis of element 113 (ununtrium), element 115 (ununpentium), or element 118 (ununoctium).


States

State (s, l, g): solid
Melting point: K   ( oC)

Boiling point: K   ( oC)

Energies

Specific heat capacity: J g-1 K-1
Heat of fusion: kJ mol-1
1st ionization energy: kJ mol-1
3rd ionization energy: kJ mol-1
Heat of atomization: kJ mol-1
Heat of vaporization : kJ mol-1
2nd ionization energy: kJ mol-1
Electron affinity: kJ mol-1

Oxidation & Electrons

Shells: 2, 8, 18, 32, 32, 18, 3
Minimum oxidation number:
Min. common oxidation no.:
Electronegativity (Pauling Scale):
Electron configuration: [Rn] 5f14 6d10 7s2 7p1
Maximum oxidation number:
Max. common oxidation no.:
Polarizability volume: Å3

Appearance & Characteristics

Structure:
Hardness: mohs


Harmful effects:
Ununtrium is harmful due to its radioactivity.

Color:

Characteristics:
Ununtrium is a synthetic radioactive metal.

Uses:
Ununtrium is of research interest only.

Reactions & Compounds

Reaction with air:
Reaction with 15 M HNO3:
Oxide(s):
Hydride(s):
Reaction with 6 M HCl:
Reaction with 6 M NaOH:
Chloride(s):

Radius

Atomic radius: pm
Ionic radius (2+ ion): pm
Ionic radius (2- ion): pm
Ionic radius (1+ ion): pm
Ionic radius (3+ ion): pm
Ionic radius (1- ion): pm

Conductivity

Thermal conductivity: W m-1 K-1
Electrical conductivity: x 106 S cm-1

Abundance & Isotopes

Abundance earth's crust: nil
Abundance solar system: parts per trillion by weight, parts per trillion by moles
Cost, pure: $ per 100g
Cost, bulk: $ per 100g

Source: Ununtrium could theoretically be produced by bombarding 243Am with 48Ca in a heavy ion accelerator. The element could theoretically also be created using a cold fusion reaction between bismuth and zinc ions. IUPAC does not accept there is enough evidence yet to accept ununtrium as an established element.

Isotopes: Ununtrium may have 6 isotopes whose half-lives are known, with mass numbers from 278 to 286. None are stable.


References

1. Lawrence Livermore National Laboratory , Livermore Scientists Team With Russia To Discover Elements 113 and 115.
2. Yuri Oganessian et al., Experiments on the Synthesis of Element 115., pdf download
3. Robert Barber, Paul Karol, Hiromichi Nakahara, Emanuele Vardaci, and Erich Vogt, Discovery of the elements with atomic numbers greater than or equal to 113,. 2011, IUPAC. (pdf download)

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