Definition of metallocenes

Organometallic coordination compounds in which one atom of a transition metal such as iron, ruthenium or osmium is bonded to and only to the face of two cyclopentadienyl [[hapto]5-(C5H5)] ligands which lie in parallel planes. NOC Rule D-2.55. The term should not be used for analogues having rings other than cyclopentadienyl as ligands.


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