Resonance-ionization mass spectrometry (RIMS) uses photons to promote an atom or molecule above its ionization potential to create an ion. Since each element has a unique energy level structure , RIMS provides a selective ionization method .

Two examples of RIMS processes

In the example on the left one photon resonantly excites an atom to an excited state and a second photon promotes the atom above its ionization potential. The example on the right shows a fully resonant three-photon RIMS process that terminates on an autoionizing level. Instrumentation Please refer to the introductory document on Mass spectrometry . Applications RIMS is useful for studying the electronic structure of atoms or molecules and to make quantitative measurements of analyte concentrations. Related topics:

  • Mass spectrometry (Intro)
  • Ionization methods
  • Ion detectors
  • Resonance-ionization spectroscopy(RIS)
  • Laser-enhanced ionization (LEI)





Search the Dictionary