The Gibbs energy of activation (![[Delta]](/img3/I_files/DDELTA.gif)
![[double dagger]](/img3/I_files/DDAGGER.gif)
G) in the limiting case where Go = 0, i.e. when the effect of thermodynamic driving force is eliminated. According to the Marcus equation, the intrinsic barrier is related to the reorganization energy, ![[lambda]](/img3/I_files/LAMBDA.gif)
, of the reaction by the equation
G = /4
CANNON (1980); SCHLESENER, AMATORE and KOCHI (1986).
Search the Dictionary
