Definition of Adduct

What is an Adduct?

An adduct is a chemical species AB, each molecular entity of which is formed by direct combination of two separate molecular entities A and B in such a way that there is change in connectivity, but no loss, of atoms within the moieties A and B. Stoichiometries other than 1:1 are also possible, e.g. a bis-adduct (2:1). An "intramolecular adduct" can be formed when A and B are groups contained within the same molecular entity.

This is a general term which, whenever appropriate, should be used in preference to the less explicit term complex. It is also used specifically for products of an addition reaction. For examples see Lewis adduct, Meisenheimer adduct, π-adduct.


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