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  #1  
Old January 23rd, 2006, 22:45
dpascali dpascali is offline
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Default EDTA/ Hardness of Water PLease i need all the help i can get

Part1: A 0.5215-g sample of CaCO3 is dissolved in 12M HCl and the resulting solution is diluted to 250.0mL in a volumetric flask.
There is a second part to this problem that has also taken me many hours to figure out how to set up.
the set up is:
25.00 mL aliquots of the solution from problem 1 are titrated with EDTA to the Eriochrome Black T end point. A blank containing a small measured amount of Mg 2+ requires 2.60 mL of the EDTA to reach the end point. An alquot to which the same amount of Mg 2+ is added requires 28.55mL of the EDTA to reach the end point.
the questions are:
a.) how many mL of EDTA are needed to titrate the Ca 2+ ion in the aliquot?
would you just add the 25.00mL and 28.55mL then subtract the 2.60 mL from that answer to get the total?
b.) how many moles of EDTA are there in the volume obtained from Part a?
PLease i need to get all the help i can get, i've been working at this for quite a few hours.
  #2  
Old January 28th, 2006, 04:22
forislam20 forislam20 is offline
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send me the whole problem and i will give u the answer!!!!!!!!!!!!!
i know much about complexation titrations
  #3  
Old February 3rd, 2006, 00:07
Tanzeela Tanzeela is offline
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Default Hardness

(Plz give the following details
1. Molarity of EDTA solution)

a.
First titrate the sample containing Ca as well as Mg using Eriochrome Black-T as indicator, Ammonia Ammonium Chloride Buffer Solution pH 10,an note the volume used.this is volume used for total Ca and Mg
b.
Now take sample, add 10 ml of 1 M NaOH, and Calcon Carboxylic Acid as Indicator and titrate with EDTA solution and note the volume used. this is the volume used only for Ca.
c.
For Mg
(Volume of EDTA used in a - Volume of EDTA used in b)
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