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Old February 22nd, 2005, 14:27
djds djds is offline
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Default Oxidation, iodation, sulfuration etc. HELP!!!

Hello! I need something about following things. It is very important to me:

1. Oxidation of carboxylic acids to chinones with presence of diiode pentaoxide (I2O5), potassium peroxodisulphate (K2S2O8), potassium permanganate (KMnO4) or potassium dichromate (K2Cr2O7);

2. Iodation. Inserting of iodium to the hydroxochinaldine acids ring by using diiode pentaoxide (I2O5);

3. Sulfuration of hydroxochinaldine acids by using tetraphosphorus decasulphide (P4S10);

4. Anything about Lawesson reagents.

I rely on your help because it is a very important case to me.
My e-mail: [email protected]
Thanks a lot!
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Old February 26th, 2005, 03:10
RobJim RobJim is offline
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Default

In your first three points, you describe chemical reactions. What is it you want to know about them?

Apparently Lawesson's reagent is p-Methoxyphenylthionophosphine sulphide dimer.

http://www.actim.com/enpll.htm

I was unable to find out more about the reagent. It's mentioned a lot on Google, but there's no site explaining what it does as far as I could tell. It's not in my o-chem textbook either.

Sorry I couldn't help you.
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