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Old February 12th, 2006, 07:04
Macak Macak is offline
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Various type of line drawings are used to represent structural information derivated from spectroscopic data. In general, the molecules are presented in some kind of perspective drawing, based on the idea that the four substituents of a tetrahedral center can be divided into two pairs, laying in mutually perpendicular planes. Most often the center and two of such substituents(atoms) are shown in the plane of the drawing (i.e. the plane of the drawing surface) and their bonds are depicted as plain lines ( ––– ). Bonds to the other two substituents(atoms) are shown with different symbols. Bonds to atoms above the plane of the drawing (coming out, toward the viewer) are shown with a bold wedge, with the narrow end of the wedge starting at the center. As an alternative bold bonds are occasionally used. Bonds to atoms below the plane (going in, away from the viewer) are shown with hash wedges. There are two separate conventions in use. In the American usage the narrow edge points to the central atom, while in the European convention, the wide edge points to the central atom. As an alternative, a set of short parallel lines is occasionally used. A broken line or an open wedge can also be found in some drawings, but their usage is discouraged.